Composition for Forming a Film on Keratin Fibres

ABSTRACT

A solid composition comprising: (a) an aminosilicone polymer, wherein the aminosilicone polymer comprises amino sidechains, and wherein the aminosilicone polymer has a weight average molecular weight of from 10,000 Dalton to 60,000 Dalton; (b) a silicone resin; (c) an ether of a water-soluble polyhydric alcohol; (d) one or more pigments or one or more coloured materials; (e) a thickening system comprising: a deposition enhancer, wherein the deposition enhancer is a hydrophilic and non-ionic polymer, and wherein the deposition enhancer has a weight average molecular weight of from 700,000 Dalton to 3,000,000 Dalton; and a thickening polymer, wherein the thickening polymer has a weight average molecular weight of at least 10,000 Dalton, and wherein the thickening polymer is a cationic thickening polymer or is a non-ionic thickening polymer. Also associated methods, kits and uses.

FIELD OF THE INVENTION

The present invention relates to the field of cosmetics, particularlyhair cosmetics, and relates to a solid composition which can be used forproviding a film on keratin fibres.

BACKGROUND OF THE INVENTION

Semi-permanent treatments to human keratin fibres are well known in theart. Of particular note are semi-permanent treatments that alter thecolour appearance of the hair or provide other coloured or reflectiveproperties via the use of glitter or particles. For example, direct dyescolour the hair in a semi-permanent fashion by adhering colouredmolecules to the keratin fibres. The dye can be later washed out. Hairchalks are powder-based or powdery products—typically provided in ablusher-style ‘compact’ or in pen format—that enable the user to applypigments and/or coloured particles to the hair.

A drawback of the known technology in this area is low adherence of thepigment or coloured material to the keratin fibres—it is a seriousconsumer concern that such products can make your clothes and/orbathroom dirty and/or stained. Furthermore, such pigment or colouredmaterial can migrate to the skin on your neck, shoulders and face andcause unsightly marks. Moreover, consumers wish to be able to apply.Chalk products typically provide a matt look, which may not be desiredby all consumers and would not provide a vibrant, shiny look where theconsumer desires this.

Thus there is a need for compositions and methods that provide moredurable means to adhere pigments and/or coloured/shiny material tokeratin fibres. In particular, there is a need for providing improveddeposition of these particles. Furthermore, there is a need forproviding a composition that is able to deposit a wide variety ofparticles—whether pigments, glitter or other coloured material. Inaddition, there is a need for such a composition that can be easilyapplied and distributed over the hair—for example does not result inclumping of the composition, or any kind of gluey-ness or gunky-ness ofany kind on the head of hair. Indeed, there is a need for a more naturallook to be provided by such means.

Teboul WO2014/001391A1, which published on 3 Jan. 2014 relates to a“process for dyeing keratin fibres, in particular the hair, whichconsists in applying to the keratin fibres:—at least one coat of atleast a first composition (i) comprising at least one hydrophobicfilm-forming polymer, at least one volatile solvent and at least onepigment, and then, after drying the said coat, at least a second coat ofat least a second composition (ii) comprising at least one hydrophobicfilm-forming polymer, at least one volatile solvent and at least onepigment . . . .”. Teboul does not disclose an aminosilicone polymercomprising an amino side chain. Maillefer et al in EP2090295A1, whichpublished on 19 Aug. 2009, mentions pigments in §127, but in the contextof a “method and composition for improving the drying time of hair”. Forexample, there is no teaching in Maillefer et al on depositionenhancers. Calaco et al in WO2013/085577A2, which published on 13 Jun.2013, mentions compositions and methods are disclosed for imparting along-wearing color to keratin fibers. However, Calaco et al also doesnot teach deposition enhancement.

None of the prior art teach or provide solutions that fulfil all theconsumers' needs in the present context.

SUMMARY OF THE INVENTION

A solid composition is provided and comprises:

-   -   (a) an aminosilicone polymer, wherein the aminosilicone polymer        comprises amino sidechains, and wherein the aminosilicone        polymer as a weight average molecular weight of from 10,000        Dalton to 60,000 Dalton;    -   (b) a silicone resin;    -   (c) an ether of a water-soluble polyhydric alcohol;    -   (d) one or more pigments or one or more coloured materials;    -   (e) a thickening system comprising:        -   a deposition enhancer, wherein the deposition enhancer is a            hydrophilic and non-ionic polymer, and wherein the            deposition enhancer has a weight average molecular weight of            from 700,000 Dalton to 3,000,000 Dalton; and        -   a thickening polymer, wherein the thickening polymer has a            weight average molecular weight of at least 10,000 Dalton,            and wherein the thickening polymer is a cationic thickening            polymer or is a non-ionic thickening polymer.            The composition may be substantially free of compounds            causing precipitation of any component of the composition            when the composition is in aqueous solution at pH 5 and at            25° C.

A method for providing a film comprising one or more pigments or one ormore coloured materials onto keratin fibres, is provided and comprisesapplying the composition as set out herein above as an aqueous solutiononto keratin fibres and allowing the keratin fibres to dry or dryingthem.

A kit is provided and comprises:

-   -   the composition as set out herein above, or a plurality of        compositions as set out herein above, wherein each composition        comprises a different pigment or coloured material;    -   an applicator.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1: Rheological measurements of compositions. X=strain (%) andY=tangent delta.

DETAILED DESCRIPTION OF THE INVENTION Definitions and General

In this document, including in all embodiments of all aspects of thepresent invention, the following definitions apply unless specificallystated otherwise. All percentages are by weight (w/w) of the totalcomposition. “wt %” means percentage by weight. All ratios are weightratios. References to ‘parts’ e.g. a mixture of 1 part X and 3 parts Y,is a ratio by weight. “QS” or “QSP” means sufficient quantity for 100%or for 100 g. +/− indicates the standard deviation. All ranges areinclusive and combinable. The number of significant digits conveysneither a limitation on the indicated amounts nor on the accuracy of themeasurements. All numerical amounts are understood to be modified by theword “about”. All measurements are understood to be made at 23° C. andat ambient conditions, where “ambient conditions” means at 1 atmosphere(atm) of pressure and at 50% relative humidity. “Relative humidity”refers to the ratio (stated as a percent) of the moisture content of aircompared to the saturated moisture level at the same temperature andpressure. Relative humidity can be measured with a hygrometer, inparticular with a probe hygrometer from VWR® International. Herein “min”means “minute” or “minutes”. Herein “mol” means mole. Herein “g”following a number means “gram” or “grams”. All amounts as they pertainto listed ingredients are based on the active level (‘solids’) and donot include carriers or by-products that may be included in commerciallyavailable materials. Herein, “comprising” means that other steps andother ingredients can be in addition. “Comprising” encompasses the terms“consisting of” and “consisting essentially of”. The compositions,formulations, methods, uses, kits, and processes of the presentinvention can comprise, consist of, and consist essentially of theelements and limitations of the invention described herein, as well asany of the additional or optional ingredients, components, steps, orlimitations described herein. Embodiments and aspects described hereinmay comprise or be combinable with elements, features or components ofother embodiments and/or aspects despite not being expressly exemplifiedin combination, unless an incompatibility is stated. “In at least oneembodiment” means that one or more embodiments, optionally allembodiments or a large subset of embodiments, of the present inventionhas/have the subsequently described feature. Where amount ranges aregiven, these are to be understood as being the total amount of saidingredient in the composition, or where more than one species fallwithin the scope of the ingredient definition, the total amount of allingredients fitting that definition, in the composition. For example, ifthe composition comprises from 1% to 5% fatty alcohol, then acomposition comprising 2% stearyl alcohol and 1% cetyl alcohol and noother fatty alcohol, would fall within this scope.

The term “molecular weight” or “M.Wt.” as used herein refers to theweight average molecular weight unless otherwise stated. The weightaverage molecular weight may be measured by gel permeationchromatography.

“Viscosity” is measured at 23° C. using a HAAKE Rotation Viscometer VT550 with cooling/heating vessel and sensor systems according to DIN53019 at a shear rate of 12.9 s⁻¹.

“Water-soluble” refers to any material that is sufficiently soluble inwater to form a clear solution to the naked eye at a concentration of0.1% by weight of the material in water at 23° C. The term“water-insoluble” refers to any material that is not “water-soluble”.

“Dry” or “substantially dry” means comprising less than 5%, less than 3%or, less than 2%, less than 1%, or about 0% of any compound orcomposition being in liquid form when measured at 23° C. at ambientconditions. Such compounds or compositions being in liquid form includewater, oils, organic solvents and other wetting agents. “Anhydrous”means that the composition comprises less than 5%, less than 3% or, lessthan 2%, less than 1%, or about 0% water by total weight of thecomposition.

“Substantially free from” or “substantially free of” means less than 1%,or less than 0.8%, or less than 0.5%, or less than 0.3%, or about 0%, bytotal weight of the composition or formulation.

“Volatile” means materials that are liquid under ambient conditions andwhich have a measurable vapour pressure at 25° C. These materials have avapour pressure greater than 1.3 Pa, or from 26.7 Pa to 5 kPa, and astandard boiling point less than 250° C., or less than 235° C., or lessthan 150° C. “Standard boiling point” is as defined by the InternationalUnion of Pure and Applied Chemistry (IUPAC).

“Hair” means mammalian keratin fibres including scalp hair, facial hairand body hair. It includes such hair still being attached to a livingsubject and also hair that has been removed therefrom such as hairswatches and hair on a doll/mannequin. “Hair” may mean human hair only.“Hair shaft” or “hair fibre” means an individual hair strand and may beused interchangeably with the term “hair.”

“Proximal to the scalp” means that portion of an extended, orsubstantially straightened, hair shaft that is closer in distance to thescalp than to the end of the hair. Thus, 50% of the hair fibre lengthwould be considered proximal to the scalp, and 50% of the hair fibrewould be distal to the scalp. “z cm proximal to the scalp” means adistance “z” along the hair, with one endpoint being on or directlyadjacent to the scalp, and the second endpoint being measured “z”centimetres along the length of the extended or substantiallystraightened hair.

“Cosmetically acceptable” means that the compositions, formulations orcomponents described are suitable for use in contact with humankeratinous tissue without undue toxicity, incompatibility, instability,allergic response, and the like. All compositions and formulationsdescribed herein which have the purpose of being directly applied tokeratinous tissue are limited to those being cosmetically acceptable.

“Derivatives” includes but is not limited to, amide, ether, ester,amino, carboxyl, acetyl, acid, salt and/or alcohol derivatives of agiven compound. “Derivatives thereof” may mean the amide, ether, ester,amino, carboxyl, acetyl, acid, salt and alcohol derivatives.

“Monomer” means a discrete, non-polymerised chemical moiety capable ofundergoing polymerisation in the presence of an initiator or anysuitable reaction that creates a macromolecule e.g. such aspolycondensation, polyaddition, anionic or cationic polymerization.“Unit” means a monomer that has already been polymerised i.e. is part ofa polymer.

“Polymer” means a chemical formed from the polymerisation of two or moremonomers. The term “polymer” shall include all materials made by thepolymerisation of monomers as well as natural polymers. Polymers madefrom only one type of monomer are called homopolymers. Herein, a polymercomprises at least two monomers. Polymers made from two or moredifferent types of monomers are called copolymers. The distribution ofthe different monomers can be random, alternating or block-wise (i.e.block copolymer). The term “polymer” used herein includes any type ofpolymer including homopolymers and copolymers.

“Kit” means a package comprising a plurality of components. “Kit” may bereferred to as “kit-of-parts”. An example of a kit is, for example, afirst composition and a separately packaged second composition andoptionally application instructions.

“Hairstyling polymer” means a hair-fixing polymer which forms a film ona surface i.e. a film-forming polymer. ‘Hairstyling polymer’ and‘film-forming polymer’ are used interchangeably in the art. In thecontext of hair science, this surface is the surface of individual hairfibres or a plurality thereof. The hairstyling polymer causes the hairfibres to be glued together to build welds, which are effectivelycrosslinks that provide the hold benefit. In concert, these welds form a‘hairnet’ to provide hair hold and volume benefits to the consumer. Whenthe net of welds is effectively formed, the hold and volume benefits canlast all day and offer good resistance to environmental humidity.

Theory Behind and Advantages of the Present Invention

The inventors provide herein a solid composition. The composition issuitable for providing a film on keratin fibres following mixture withsolvent, more particularly with the aim of providing a coloured film onkeratin fibres. The composition is herein provided in solid form forease of use and storage for the consumer/stylist and ease of shipment.Indeed, in a solid context, the composition can be provided for examplein powdered or granulated form, which means that the composition keepsfor a longer time and issues with preservation and storage areminimised. Furthermore, the composition is lighter in weight and soshipment becomes more economical. Moreover, a variety of solidcompositions can be provided as a kit, each kit containing a pluralityof compositions according to the present invention wherein eachcomposition comprises a different pigment or coloured material. Hence,the consumer or stylist can select the desired colour or effect to matchthe colour of the hair in question and/or vis-à-vis other factors suchas skin tone, outfit and event.

It is expected that the consumer/stylist will provide solvent and mixthe composition with said solvent prior to application onto the keratinfibres. Indeed, the combination of film-forming aminosilicone polymer,silicone resin, ether of a water-soluble polyhydric alcohol, andselected thickening system, after mixing with solvent, results in a filmon keratin fibres, particularly human head hair, that is sufficientlydurable that it does not quickly rub off whilst on the keratin fibres,for example on the hands, clothes etc of the consumer, nor does itprovide bad hair feel, such as lumpiness, nor abrasiveness, nor weighdown the hair reducing the head of hair volume, nor unsightly globules.

Indeed, the film-forming aminosilicone polymer and silicone resin enablethe forming of a very thin, dry film, which tightly binds any colouredmaterial and/or pigment onto the hair fibres in a durable fashion. Theaminosilicone polymer and silicone resin provides an excellent film viaa crosslinking and dehydration mechanism.

The selected thickening system can help to prevent dripping of thecomposition by inhibiting capillary action, which would otherwisequickly draw the composition down the fibres and onto the floor and/orclothes of the user. Nevertheless, the thickening system, particularlythe combination of thickening polymer and deposition enhancer, providesa non-dripping composition that adheres well to keratin fibres withoutgenerating a sticky feel. Moreover, the thickening system does notdetract from the ability of the film-forming aminosilicone polymer andsilicone resin to provide the thin, dry film.

In particular, the present invention overcomes the drawbacksdemonstrated by previous developments in this area in that it is able toprovide subtle hair effects that can be employed by a much wider varietyof end-consumers in a wider variety of life contexts. In other words,the effects provided by the present invention are not limited to highlyvibrant and dazzling hair effects that are often used prior to visitinga disco or nightclub, but also provide chic hair looks that areacceptable in a business context and also not too overpowering foreveryday hair looks.

Indeed, the selected combination of features—the combination offilm-forming aminosilicone polymer, silicone resin, ether of awater-soluble polyhydric alcohol, and selected thickeningsystem—provides an excellent support system for coloured material and/orpigments, which can provide the desired effects to the hair, such asglitteriness, colour, shininess etc. Said coloured material and/orpigments may be provided separately from the composition chassis suchthat the consumer and/or stylist can select the exact the exact type ofpigment and/or coloured material desired.

Composition of the First Aspect

The composition is a solid composition. “Solid” means that the moleculesof the composition do flow over each other to take on the shape of thecontainer like a liquid does, nor do they expand away from each other tofill the entire volume available like a gas does. The composition may bein powder form. The composition may be in granule form. The compositionmay be dry, or may be anhydrous.

The composition may be in unit dose form. “Unit dose” means that thecomposition is separated into amount suitable for one head of hair orapplication. The composition may be in tablet form. Said tablet may becube or cuboid in shape.

After mixing with solvent the composition is for providing a film onkeratin fibres. The composition may be, after mixing with solvent, forproviding a film comprising pigment or coloured material on keratinfibres. The film may be a durable film. The solid composition may becosmetically acceptable.

The composition is substantially free of compounds causing precipitationof any component of the composition when the composition is in aqueoussolution at pH 5 and at 23° C.

When the composition typically comprises a film-forming aminosiliconepolymer, a MQ resin, a thickening system comprising a depositionenhancer and a thickening polymer, and a solvent, the pH of thecomposition may be between 4 and 6, preferably between 4.5 and 5.5.Examples of compounds causing precipitation of any component of thecomposition when the composition is in aqueous solution at pH 5 and at23° C. may be a basic solvent, or ionic compounds or compounds that arecationic from pH 4 to 6, preferably from pH 5 to 6 or compounds having arelative ionic strength.

Indeed, precipitation of any component of the present composition wouldhave negative side effects on the efficacy of the presentinvention—particularly in terms of hair feel. Indeed, with the exclusionof the pigment and/or coloured material that is herein intended to beimmobilised on hair, other residues on hair are not accepted by theconsumer. For example, precipitation of the film-forming aminosiliconepolymer and/or silicone resin would detract from their ability to form afilm on the hair fibres and would form residues on hair. The compositionmay be substantially free of any further ionic compounds. Thecomposition may be substantially free of any compounds that are cationicat pH 4.0 to 5.0.

Aminosilicone & Silicone Resin

The composition comprises a film-forming aminosilicone polymer, whereinthe aminosilicone polymer comprises amino side chains, and wherein theaminosilicone polymer has a weight average molecular weight of from10,000 Dalton to 60,000 Dalton. “Sidechain” (aka “side chain”) in thecontext of a silicone refers to a group being not part of the siliconebackbone nor only present on at least one terminus of the siliconebackbone. “Terminal aminosilicone” as defined herein means siliconecomprising one or more amino groups at one or both ends of the siliconebackbone Aminosilicone polymers having amino side chains are sometimesreferred to as silicone compounds comprising pendant amino groups. Theaminosilicone polymer may be not a terminal aminosilicone. Thecomposition may be substantially free of silicones having terminal aminogroups.

The aminosilicone polymer is a film-forming aminosilicone polymer. Theaminosilicone polymer may be a polydimethylsiloxane having graft aminogroups.

The aminosilicone polymer may be a weight average molecular weight offrom 15,000 Dalton to 50,000 Dalton, or from 20,000 Dalton to 40,000Dalton.

The aminosilicone polymer may be a polydimethylsiloxane polymer havingpendent (graft) amino groups. The aminosilicone polymer conforms to theformula:

. . . in which x′ and y′ are integers such that the weight averagemolecular weight is between 10,000 Dalton and 60,000 Dalton. The endcapsmay be methoxy rather than hydroxyl as pictured in the above formula.

The aminosilicone polymer may be a polydimethylsiloxane polymer having asidechain with from 3 to 8 carbon atoms. The sidechain may comprise,preferably may consist of carbon, hydrogen and nitrogen atoms. Theaminosilicone polymer may be a polydimethylsiloxane polymer having anaminoethyl aminopropyl sidechain. The aminosilicone polymer may conformto the formula:

. . . in which n and m are integers such that the weight averagemolecular weight is between 10,000 Dalton and 60,000 Dalton, R₁ and R₃are independently selected from —OH or —OCH₃; R₂ is H or a C₁ to C₃alkyl, or methyl or H, preferably methyl. “n” may be on average from 1to 50, or from 5 to 20, or from 6 to 10, or from 8 to 9, and “m” may beon average from 120 to 300, or from 150 to 200. “n” may be on averagefrom 5 to 8, “m” may be on average from 150 to 180, R₁ and R₃ may beboth methyl, and R₃ is —OCH₃.

The aminosilicone polymer may have an amine number of from 0.1 meq/g to3 meq/g, or from 0.7 meq/g to 2.5 meq/g, or from 0.6 meq/g to 1 meq/g.

Suitable example aminosilicone polymers can be found in the followingpatent documents, which are incorporated herein by reference: DecosterU.S. Pat. No. 6,451,747B1 col. 17, 11.4-27; Hughes U.S. Pat. No.5,567,428 co1.13, 11.40-56; Gawtrey et al US2004/0010863A1, §0016 to§0039; Mahr et al US2006/0041026A1.

The solid composition may comprise from 5% to 35%, or from 10% to 25% ofthe aminosilicone polymer. The composition as applied to hair maycomprise from 1% to 15%, or from 1.5% to 5% of the aminosiliconepolymer. The viscosity of the aminosilicone polymer may be from 10 to100,000 mPa·s, or from 100 to 10,000 mPa·s.

The composition may comprise a silicone resin. Silicone resins are knownin the art. The silicone resin may be a film-forming polymer. Thesilicone resin may be an MQ resin. “M” stands for Me₃SiO and “Q” standsfor SiO₄. The MQ resin may have an M:Q molar ratio of from 0.5:1.0 to1.5:1.0. The weight average molecular weight of the resin may be from1000 Daltons to 10,000 Daltons. The MQ resin may contain at least 80mol. %, or at least 95 mol. %, of units of the general formulae below:

R⁷ ₃SiO_(1/2)

SiO_(4/2)

in which R⁷ is C₁₋₄₀ alkyl, H, —OR or —OH radicals. The ratio of theunits of the general formulae may be from 0.5 to 2.0, or from 0.5 to1.5. The not more than 3% by weight, or not more than 2.5% by weight, ofthe radicals R⁷ may be —OR and —OH.

The remaining units of the MQ silicone resin may be units of thefollowing general formulae:

R⁷ ₂SiO_(2/2)

R⁷SiO_(3/2)

in which R⁷ is C₁₋₄₀ alkyl, H, —OR or —OH radicals.

R⁷ may be C₁₋₄₀ alkyl that is optionally halogen-substituted, linear,cyclic, branched, aromatic, saturated or unsaturated. R⁷ may be an alkylgroup having C₁₋₆ carbon atoms, or a phenyl radical. The halogensubstituents may be selected from fluorine and chlorine. R⁷ may beselected from methyl, ethyl, phenyl and H. The solid composition maycomprise from 0.5% to 10%, or from 1% to 6% MQ resin. The composition asapplied to hair may comprise from 0.1% to 10%, or from 1% to 5%, or from2% to 4% MQ resin.

MQ resins are available from Wacker-Chemie AG, D-81737 München, Germany.For example, MQ-RESIN POWDER 803 TF is a co-hydrolysis product oftetraalkoxy silane (Q unit) and trimethyl-ethoxy silane (M unit) and canbe seen as a three dimensional network of polysilicic acid units whichare endblocked with trimethylsilyl groups. Some residual ethoxy andhydroxy functions are present. MQ resins are also available from DowCorning. For example, Dow Corning® MQ-1640 Flake Resin is a combinationof MQ and T propyl silicone resin and has the INCI name: Trimethylsiloxysilicate (and) Polypropyl silsesquioxane.

The composition comprises an ether of a water-soluble polyhydricalcohol. The ether of a water-soluble polyhydric alcohol has theadvantage that it is able to prevent the aminosilicone and the siliconeresin from forming a complex. The ether of a water-soluble polyhydricalcohol may be a non-polymeric, amphiphilic compound. Indeed, theaminosilicone comprises amino side chains, which lend hydrophiliccharacter to the aminosilicone, and the silicone resin typically ishydrophobic in nature. Thus where the ether of a water-solublepolyhydric alcohol has amphiphilic chemistry it can interact with boththe aminosilicone and the silicone resin and keep them from clumping,and also from precipitating. The composition may comprise an ether of awater-soluble polyhydric alcohol, wherein the ether of a water-solublepolyhydric alcohol is selected from the group consisting of diethyleneglycol monobutyl ether, ethylene glycol monohexyl ether, and a mixtureof diethylene glycol monobutyl ether and ethylene glycol monohexylether. The solid composition may comprise from 10% to 20%, or from 12%to 18% ether of a water-soluble polyhydric alcohol. The composition asapplied to hair may comprise from 0.01% to 20%, or from 0.1% to 10%, orfrom 0.5% to 5%, or from 1.0% to 5%, or from 2% to 5% ether of awater-soluble polyhydric alcohol. Ethylene glycol monohexyl ether has aninitial boiling point of 208.5° C. at atmospheric pressure. Diethyleneglycol monobutyl ether has an initial boiling point of 226° C. atatmospheric pressure.

A suitable product for use in the present invention is available underthe trade mark Wacker®/BELSIL ADM 8301 E by the company Wacker-ChemieAG, D-81737 München, Germany. This product contains from 10% to 20% ofpoly [3-((2-aminoethyl)amino)propyl]lmethyl(dimethyl)siloxane,hydroxyterminated, which is an aminosilicone. It also contains from 0.1%to 0.2% octamethylcyclotetrasiloxane and from 1% to 5% of an MQ siliconeresin. The product also contains from 1% to 3% ethylene glycol monohexylether and from 5% to 10% diethyleneglycol monobutyl ether. Said productis described in US2006/0041026A1 which is incorporated herein byreference. A similar product is Wacker HC303 also from Wacker-Chemie AG.

Thickening System

The composition comprises a thickening system. The thickening systemcomprises a deposition enhancer and a thickening polymer. The solidcomposition may comprise from 5% to 12%, or from 6% to 10% of thethickening system. The composition as applied to hair may comprise from0.5% to 2% thickening system.

The thickening system comprises a deposition enhancer. The depositionenhancer is a hydrophilic and non-ionic polymer, and wherein thedeposition enhancer has a weight average molecular weight of from700,000 Dalton to 3,000,000 Dalton. The deposition enhancer is usefulfor aiding the deposition of the aminosilicone and silicone resin aswell as any pigment and/or coloured material on to the hair fibre. Inparticular, the deposition enhancer has the advantage that moreaminosilicone and silicone resin as well as any pigment and/or colouredmaterial stays on the hair fibre rather than dripping or sliding off thehair fibre. Indeed, in view of the physical structure of a head of hairi.e. a plurality of fibres that are close proximity to one another,capillary action plays a role with regards to fluids on hair. Hence, thedeposition enhancer is useful for preventing the capillary action fromstripping the aminosilicone, silicone resin and any pigment and/orcoloured material from the hair.

The solid composition may comprise from 0.1% to 2% of the depositionenhancer. The composition as applied to hair may comprise from 0.01% to5% of the deposition enhancer. The composition as applied to hair maycomprise from 0.05% to 4%, or from 0.075% to 3.5%, or from 0.1% to 3%,or from 0.1% to 2%, or from 0.15% to 1% of the deposition enhancer.

The deposition enhancer may conform to the formula H(OCH₂CH₂)_(n)OHwherein n has an average value of from 20,000 to 50,000. The depositionenhancer may conform to the formula H(OCH₂CH₂)_(n)OH wherein n has anaverage value of from 40,000 to 50,000. The composition as applied tohair may comprise from 0.01% to 5% of the deposition enhancer. Thecomposition as applied to hair may comprise from 0.05% to 4%, or from0.075% to 3.5%, or from 0.1% to 3%, or from 0.1% to 2%, or from 0.15% to1% of the deposition enhancer, wherein the deposition enhancer conformsto the formula H(OCH₂CH₂)_(n)OH wherein n has an average value of from40,000 to 50,000.

The deposition enhancer may have a weight average molecular weight offrom 1,000,000 Dalton to 2,500,000 Dalton.

Useful deposition enhancers are available from Dow under their POLYOXbrand. POLYOX water-soluble resins from Dow are produced and supplied aswhite, granular powders. In particular, POLYOX WSR N-60K is PEG-45M i.e.formula H(OCH₂CH₂)_(n)OH wherein n is an integer and where n has anaverage value of 45,000. PEG-45M has a weight average molecular weightof 2,000,000 Dalton. Also useful is POLYOX WSR N-12K, which is PEG-23Mi.e. formula H(OCH₂CH₂)_(n)OH wherein n is an integer where n has anaverage value of 23,000. PEG-23M has a weight average molecular weightof 1,000,000 Dalton. Also useful is POLYOX WSR-1105, which has a weightaverage molecular weight of 900,000 Dalton.

The thickening system comprises a thickening polymer. The thickeningpolymer has a weight average molecular weight of at least 10,000 Dalton.The thickening polymer is a cationic thickening polymer or is anon-ionic thickening polymer. The solid composition may comprise from 4%to 15%, or from 7% to 10% of the thickening polymer. The composition asapplied to hair may comprise from 0.01% to 5% of the thickening polymer.The composition as applied to hair may comprise from 0.1%, or from 0.2%,or from 0.3%, or from 0.4, or from 0.5%, or from 0.6%, or from 0.7%, orfrom 0.8%, or from 0.9% to 5%, or to 4.5%, or to 4%, or to 3.5%, or to3%, or to 2.5%, or to 2%, or to 1.5% of the thickening polymer. Thethickening polymer may be a non-ionic thickening polymer.

The thickening polymer may be a polysaccharide. The thickening polymermay be a polysaccharide and the polysaccharide may be selected from thegroup consisting of hydroxyethylcellulose, hydroxypropylcellulose,starch compounds, xanthan gum, carrageenans, and mixtures thereof. Thethickening polymer may be a heteropolysaccharide. The totalpolysaccharide content present in the composition as applied to hair maybe from 0.2% to 5%, or from 0.5% to 4%. Suitable polysaccharides andheteropolysaccharides include starches and derivatives thereof, e.g.mono- or di-esters with phosphoric acid, cellulose types and theirderivatives, xanthan gums, carrageenans. Heteropolysaccharides includexanthan gum such as Keltrol® from Kelco, and Natrosol® 250 HHR fromHerkules. The viscosity-increasing agent may be a starch compound. Theviscosity-increasing agent may be a hydroxypropyl starch phosphate. Anexample of a hydroxypropyl starch phosphate is Structure® XL from AkzoNobel. The thickening polymer may be a hydroxethyl cellulose. Thehydroxethyl cellulose may conform to the formula below:

A suitable hydroxethyl cellulose is Cellosize™ HEC QP 4400 from Dow.

The thickening polymer may be a cationic thickening polymer. Thethickening polymer may comprise a hydrocarbon backbone substituted withan amino-group containing sidechain. The thickening polymer may be acationic thickening polymer comprising a quaternary amine group,alternatively a quaternary ammonium group. The thickening polymer mayhave the below structure:

The thickening polymer may be a Polyquaternium-37. Polyquaternium-37 isa poly(2-methacryloxyethyltrimethylammonium chloride). Polyquaternium-37is available from BASF via the product Salcare® SC 96 FROM BASF, whichhas the INCI name: Polyquaternium-37 (and) Propylene Glycol DicaprateDicaprylate (and) PPG-1 Trideceth-6. Polyquaternium-37 is also availableas: Syntran PC 5320 (Interpolymer Corporation); Ultragel® 300 fromCognis GmbH; OriStar PQ37 from Orient Stars LLC; Synthalen CN from 3VGroup; Synthalen CR from 3V Group; Synthalen CU from 3V Group; Cosmedia®Triple C from Cognis GmbH, which has the INCI: Polyquaternium-37,Dicaprylyl Carbonate, Lauryl Glucoside.

Where the composition comprises a thickening polymer being a cationicthickening polymer comprising a quaternary amine group, alternatively aquaternary ammonium group, the composition as applied to hair may have apH in the range from 3 to 5, or from 3.5 to 4.5. The pH range is usefulin ensuring that the thickening polymer does not act as a nucleophile.

Pigments

The composition comprises one or more pigments. The one or more pigmentsmay be one or more coloured pigments which impart colour effects to theproduct mass or to the hair, or they may be lustre effect pigments whichimpart desirable and aesthetically pleasing lustre effects to thecomposition or to the keratin fibres. The colour or lustre effects onthe hair are preferably temporary, i.e. they last until the next hairwash and can be removed again by washing the hair with customaryshampoos.

The composition comprises pigment having a D₅₀ particle diameter of from5 micron to 60 micron. Particle diameter is represented by D₅₀, which isthe median diameter by volume. D₅₀ is measured with a MalvernMastersizer 2000, which is a laser diffraction particle sizer and it ismeasured according to ISO 13320:2009(en) with Hydro 2000G or Hydro 2000Swhere the dispersant is water or ethanol. Detection range is from 0.02micron to 2000 micron. D₅₀ is expressed as x₅₀ in ISO 13320:2009(en).Laser diffraction measures particle size distributions by measuring theangular variation in intensity of light scattered as a laser beam passesthrough a dispersed particulate sample analyser and the particle size isreported as a volume equivalent sphere diameter. A discussion ofcalculating D₅₀ is provided in Barber et al, Pharmaceutical Developmentand Technology, 3(2), 153-161 (1998), which is incorporated herein byreference.

The composition may comprise one or more pigments having a D₅₀ particlediameter of from 10 micron to 40 micron. The one or more pigments may bepresent in the composition in undissolved form. The solid compositionmay comprise from 40% to 60%, or from 45% to 55% of the one or morepigments. The composition as applied to hair may comprise from 0.01% to25%, or from 0.1% to 20% of the one or more pigments, or from 1% to 15%,or from 4% to 10% of the one or more pigments.

The one or more pigments may be colorants which are virtually insolublein the composition, and may be inorganic or organic. Inorganic-organicmixed pigments are also possible. The composition may comprise one ormore inorganic pigments. The advantage of inorganic pigments is theirexcellent resistance to light, weather and temperature. The one or moreinorganic pigments may be of natural origin, and are, for example,derived from material selected from the group consisting of chalk,ochre, umber, green earth, burnt sienna, and graphite.

The one or more pigments may be one or more white pigments, such as, forexample, titanium dioxide or zinc oxide, or may be one or more blackpigments, such as, for example, iron oxide black, or may be one or morecoloured pigments, such as, for example, ultramarine or iron oxide red,lustre pigments, metal effect pigments, pearlescent pigments, andfluorescent or phosphorescent pigments. The one or more pigments may beone or more coloured, non-white pigments. The one or more pigments maybe selected from the group consisting of metal oxides, hydroxides andoxide hydrates, mixed phase pigments, sulfur-containing silicates, metalsulfides, complex metal cyanides, metal sulfates, chromates andmolybdates, and the metals themselves (bronze pigments). The one or morepigments may be selected from the group consisting of are titaniumdioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI77492), red and brown iron oxide (CI 77491), manganese violet (CI77742), ultramarine (sodium aluminium sulfosilicates, CI 77007, PigmentBlue 29), chromium oxide hydrate (CI 77289), Prussian blue (ferricferrocyanide, CI 77510), carmine (cochineal), and combinations thereof.

The one or more pigments may be one or more pearlescent and colouredpigments based on mica which are coated with a metal oxide or a metaloxychloride, such as titanium dioxide or bismuth oxychloride, andoptionally further colour-imparting substances, such as iron oxides,Prussian blue, ultramarine, and carmine The colour exhibited by thepigment can be adjusted by varying the layer thickness. Such pigmentsare sold, for example, under the trade names Rona®, Colorona ®,Dichrona®, RonaFlair®, Ronastar®, Xirona® and Timiron® all of which areavailable from Merck, Darmstadt, Germany For example, Xirona® is a brandfor colour travel pigments that display colour shifting effectsdepending on the viewing angle and are based on either natural mica,silica (SiO₂) or calcium aluminium borosilicate flakes, coated withvarying layers of titanium dioxide (TiO₂).

Pigments from the line KTZ® from Kobo Products, Inc., 3474 So. ClintonAve., So. Plainfield, USA, are also useful herein, in particular theSurface Treated KTZ® Pearlescent Pigments from Kobo. Particularly usefulare KTZ® FINE WHITE (mica and TiO₂) having a D₅₀ particle diameter of 5to 25 micron and also KTZ® CELESTIAL LUSTER (mica and TiO₂, 10 to 60micron) as well as KTZ® CLASSIC WHITE (mica and TiO₂, 10 to 60 micron).Also useful are SynCrystal Sapphire from Eckart Effect Pigments, whichis a blue powder comprising platelets of synthetic fluorphlogopitecoated with titanium dioxide, ferric ferrocyanide and small amounts oftin oxide. Also useful is SYNCRYSTAL Almond also from Eckart, which is abeige powder with a copper reflection colour and is composed ofplatelets of synthetic fluorphlogopite and coated with titanium dioxideand iron oxides. Also useful is Duocrome® RV 524C from BASF, whichprovides a two colour look via a lustrous red powder with a violetreflection powder due to its composition of mica, titanium dioxide andcarmine.

The one or more pigments may be one or more organic pigments. The one ormore organic pigments may be selected from the group consisting ofnatural pigments sepia, gamboge, bone charcoal, Cassel brown, indigo,chlorophyll and other plant pigments. The one or more organic pigmentsmay be one or more synthetic organic pigments which are selected fromthe group consisting of azo pigments, anthraquinoids, indigoids,dioxazine, quinacridone, phthalocyanine, isoindolinone, perylene andperinone, metal complex, alkali blue, diketopyrrolopyrrole pigments, andcombinations thereof.

The one or more pigments may be selected from the group consisting ofiron oxide, titanium dioxide, mica, borosilicate, and combinationsthereof. The one or more pigments may comprise an iron oxide (Fe₂O₃)pigment. The one or more pigments may comprise a combination of mica andtitanium dioxide.

Coloured Material

The composition comprises one or more coloured materials. The one ormore coloured material may be particulate in form. The one or morecoloured material may be selected from the group consisting of colouredfibres, coloured beads, coloured particles such as nano-particles,coloured polymers comprising covalently attached dyes, liquid crystals,particles having diffraction properties, UV absorber and photoprotectivesubstances, pressure- or light-sensitive pigments, and combinationsthereof.

The one or more coloured materials may be capable of changing colour viaa mechanism selected from the group consisting of thermochromism,photochromism, hydrochromism, magnetochromism, electrochromism,piezochromism, chemichromism, mechano-optics. Suitable materials include3D Magnetic Pigments, Glow Dust, Fluorescent Pigments, Thermo Dust,Chameleon Pigments and other colour changing materials from Solar ColorDust (http://solarcolordust.com/).

The composition may comprise one or more photoprotective substances. Thecomposition as applied to hair may comprise from 0.01 to 10%, or from0.1 to 5%, or from 0.2 to 2% of the one or more photoprotectivesubstances. Useful photoprotective substances are specified inEP1084696A1 from §0036 to §0053, which is incorporated herein byreference. The one or more photoprotective substances may be selectedfrom the group consisting of 2-ethylhexyl 4-methoxy-cinnamate, methylmethoxycinnamate, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid,polyethoxylated p-aminobenzoates, di-butyl-hydroxytoluene (BHT), andmixtures thereof.

The composition as applied to hair may comprise from 0.01% to 10%, orfrom 0.05% to 5% of one or more particulate substances. The one or moreparticulate substances may be substances which are solid at roomtemperature (23° C.) and are in the form of particles. The one or moreparticulate substances may be selected from the group consisting ofsilica, silicates, aluminates, clay earths, mica, and insoluble salts.The one or more particulate substances may be selected from the groupconsisting of insoluble inorganic metal salts, metal oxides, mineralsand insoluble polymer particles. The one or more particulate substancesmay be titanium dioxide.

The one or more particulate substances may be present in the compositionin undissolved, or stably dispersed form, and, following application tothe hair and evaporation of the solvent, can deposit on the hair insolid form.

The one or more particulate substances may be selected from the groupconsisting of silica (silica gel, silicon dioxide) and metal salts, inparticular inorganic metal salts. The one or more particulate substancesmay be silica. The one or more particulate substances may be selectedfrom the group consisting of metal salts such as alkali metal oralkaline earth metal halides, e.g. sodium chloride or potassiumchloride; alkali metal or alkaline earth metal sulfates, such as sodiumsulfate or magnesium sulfate.

Preservative

The composition may comprise at least one preservative and/or a mixtureof preservatives. The preservative and/or mixture of preservatives maybe active against gram negative bacteria, Staphylococcus aureus andCandida albicans. The composition may comprise 2-phenoxyethanol and/orphenylmethanol. The composition may comprise 2-phenoxyethanol. Thecomposition may comprise from 0.01% to 5% of the preservative, or from0.1% to 2%, or from 0.5% to 1.5% of the preservative. The preservativemay be selected from the group consisting of benzyl alcohol,phenoxyethanol, and mixtures thereof. The composition may comprise atleast one preservative; and wherein the preservative may be selectedfrom the group consisting of benzyl alcohol and phenoxyethanol; orwherein the preservative may be a mixture of benzyl alcohol andphenoxyethanol.

The composition may be substantially free of esters ofparahydroxybenzoic acid. Esters of parahydroxybenzoic acid are commonlyknown as parabens. Parabens are not preferred by some consumers. Thecomposition may be substantially free of isothiazolinone compounds. Thecomposition may be substantially free of benzoate compounds. Benzoatecompounds are not preferred in view of the potential for instabilityand/or precipitation of the composition. The composition may besubstantially free of1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione.

The composition may be substantially free of preservative.

Perfume

The composition may comprise one or more perfumes. The composition maycomprise from 0.001% to 2% of the one or more perfumes. The one or morepigments and/or the one or more coloured materials may have perfumedcoating. The one or more perfumes may also be provided via anencapsulated perfume i.e. a perfume provided inside a microcapsule.

The microcapsule may feature friction-triggered release technology i.e.the contents of the microcapsule is released upon exposing themicrocapsule friction. Said friction could be the action of sponging thecomposition according to the present invention onto the hair or combingthe hair after the composition has been applied. The microcapsule may bea friable microcapsule. A friable microcapsule is configured to releasethe core material when the outer shell is ruptured. The microcapsule maycomprise a shell made from a synthetic polymeric material. Themicrocapsule may comprise a core material and a shell surrounding thecore material, wherein the shell comprises: a plurality of aminemonomers selected from the group consisting of aminoalkyl acrylates,alkyl aminoalkyl acrylates, dialkyl aminoalkyl acrylates, aminoalkylmethacrylates, alkylamino aminoalkyl methacrylates, dialkyl aminoalkylmethacrylates, tertiarybutyl aminoethyl methacrylates, diethylaminoethylmethacrylates, dimethylaminoethyl methacrylates, dipropylaminoethylmethacrylates, and mixtures thereof; and a plurality of multifunctionalmonomers or multifunctional oligomers.

The shell may comprise, preferably may consist of a polyacrylatematerial, such as a polyacrylate random copolymer. The microcapsule mayfeature moisture-triggered release technology i.e. the contents of themicrocapsule is released upon contact with moisture. The microcapsulemay comprise cyclic oligosaccharides, or the microcapsule matrix orshell is made from cyclic oligosaccharides. “Cyclic oligosaccharide”means a cyclic structure comprising six or more saccharide units. Thecyclic oligosaccharides may have six, seven, or eight saccharide unitsor combinations thereof. It is common in the art to refer to six, sevenand eight membered cyclic oligosaccharides as α, β, and γ, respectively.The cyclic oligosaccharides may be selected from the cyclodextrins:methyl-α-cyclodextrins, methyl-β-cyclodextrins,hydroxypropyl-α-cyclodextrins, hydroxypropyl-β-cyclodextrins, andmixtures thereof. The cyclodextrins may be in the form of particles. Thecyclodextrins may also be spray-dried.

The one or more perfumes may be an animal fragrance or a plantfragrance. The animal fragrance may be selected from consisting of muskoil, civet, castoreum, ambergris, and mixtures thereof. The plantfragrance may be selected from consisting of nutmeg extract, cardomonextract, ginger extract, cinnamon extract, patchouli oil, geranium oil,orange oil, mandarin oil, orange flower extract, cedarwood, vetyver,lavandin, ylang extract, tuberose extract, sandalwood oil, bergamot oil,rosemary oil, spearmint oil, peppermint oil, lemon oil, lavender oil,citronella oil, chamomille oil, clove oil, sage oil, neroli oil,labdanum oil, eucalyptus oil, verbena oil, mimosa extract, narcissusextract, carrot seed extract, jasmine extract, olibanum extract, roseextract, and mixtures thereof.

The one or more perfumes may be selected from the group consisting ofacetophenone, adoxal, aldehyde C-12, aldehyde C-14, aldehyde C-18, allylcaprylate, ambroxan, amyl acetate, dimethylindane derivatives,a-amylcinnamic aldehyde, anethole, anisaldehyde, benzaldehyde, benzylacetate, benzyl alcohol and ester derivatives, benzyl propionate, benzylsalicylate, borneol, butyl acetate, camphor, carbitol, cinnamaldehyde,cinnamyl acetate, cinnamyl alcohol, cis-3-hexanol and ester derivatives,cis-3-hexenyl methyl carbonate, citral, citronnellol and esterderivatives, cumin aldehyde, cyclamen aldehyde, cyclo galbanate,damascones, decalactone, decanol, estragole, dihydromyrcenol, dimethylbenzyl carbinol, 6,8-dimethyl-2-nonanol, dimethyl benzyl carbinylbutyrate, ethyl acetate, ethyl isobutyrate, ethyl butyrate, ethylpropionate, ethyl caprylate, ethyl cinnamate, ethyl hexanoate, ethylvalerate, ethyl vanillin, eugenol, exaltolide, fenchone, fruity esterssuch as ethyl 2-methyl butyrate, galaxolide, geraniol and esterderivatives, helional, 2-heptonone, hexenol, a-hexylcinnamic aldehyde,hydroxycitrolnellal, indole, isoamyl acetate, isoeugenol acetate,ionones, isoeugenol, isoamyl iso-valerate, iso E super, limonene,linalool, lilial, linalyl acetate, lyral, maj antol, mayol, melonal,menthol, p-methylacetophenone, methyl anthranilate, methyl cedrylone,methyl dihydrojasmonate, methyl eugenol, methyl ionone,methyl-α-naphthyl ketone, methylphenylcarbinyl acetate, mugetanol,γ-nonalactone, octanal, phenyl ethyl acetate, phenyl-acetaldehydedimethyl acetate, phenoxyethyl isobutyrate, phenyl ethyl alcohol,pinenes, sandalore, santalol, stemone, thymol, terpenes, triplal,triethyl citrate, 3,3,5-trimethylcyclohexanol, γ-undecalactone,undecenal, vanillin, veloutone, verdox, and mixtures thereof.

Hair Colouring Agent

The composition may further comprise a hair colouring agent. The haircolouring agent may be a direct dye. The composition may comprise atotal amount of from 0.001% to 4%, or from 0.005% to 3%, or from 0.01%to 2% direct dye. The presence of a direct dye and the proportionthereof can be useful in that it can provide or enhancecolouring/dyeing, particularly with regard to intensity.

The direct dye may be selected from the group consisting of nitro dyesto provide a blue colour, nitro dyes to provide a red colour, nitro dyesto provide a yellow colour, quinone dyes, basic dyes, neutral azo dyes,acid dyes, and mixtures thereof. The direct dye may be a nitro dye toprovide a blue colour. The direct dye may be a nitro dye to provide ared colour. The direct dye may be a nitro dye to provide a yellowcolour. The direct dye may be a quinone dye. The direct dye may be abasic dye. The direct dye may be a neutral azo dye. The direct dye maybe an acid dye. The direct dye may be selected from the group consistingof Acid dyes such as Acid Yellow 1, Acid Orange 3, Acid Black 1, AcidBlack 52, Acid Orange 7, Acid Red 33, Acid Yellow 23, Acid Blue 9, AcidViolet 43, Acid Blue 16, Acid Blue 62, Acid Blue 25, Acid Red 4, BasicDyes such as Basic Brown 17, Basic Red 118, Basic Orange 69, Basic Red76, Basic Brown 16, Basic Yellow 57, Basic Violet 14, Basic Blue 7,Basic Blue 26, Basic Red 2, Basic Blue 99, Basic Yellow 29, Basic Red51, Basic Orange 31, Basic Yellow 87,4-(3-(4-amino-9,10-dioxo-9,10-dihydroanthracen-1-ylamino)propyl)-4-methylmorpholin-4-ium-methylsulfate,(E)-1-(2-(4-(4,5-dimethylthiazol-2-yl)diazenyl)phenyl)(ethyl)amino)ethyl)-3-methyl-1H-imidazol-3 -ium chloride,(E)-4-(2-(4-(dimethylamino)phenyl)diazenyl)-1-methyl-1H-imidazol-3-ium-3-yl)butane-1-sulfonate ,(E)-4-(4-(2-methyl-2-phenylhydrazono)methyl)pyridinium-1-yl)butane-1-sulfonate,N,N-dimethyl-3 -(4-(methylamino)-9,10-dioxo-4 a,9,9 a,10-tetrahydroanthracen-1-ylamino)-N-propylpropan-1-aminium bromide, Disperse Dyessuch as Disperse Red 17, Disperse Violet 1, Disperse Red 15, DisperseViolet 1, Disperse Black 9, Disperse Blue 3, Disperse Blue 23, DisperseBlue 377, Nitro Dyes such as 1-(2-(4-nitrophenylamino)ethyl)urea,2-(4-methyl-2-nitrophenylamino)ethanol, 4-nitrobenzene-1,2-diamine,2-nitrobenzene-1,4-diamine, Picramic acid, HC Red No. 13,2,2′-(2-nitro-1,4-phenylene)bis(azanediyl)diethanol, HC Yellow No. 5, HCRed No. 7, HC Blue No.2, HC Yellow No. 4, HC Yellow No. 2, HC Orange No.1, HC Red No. 1, 2-(4-amino-2-chloro-5-nitrophenylamino)ethanol, HC RedNo. 3, 4-amino-3-nitrophenol, 4-(2-hydroxyethylamino)-3-nitrophenol,2-amino-3-nitrophenol, 2-(3-(methylamino)-4-nitrophenoxy)ethanol,3-(3-amino-4-nitrophenyl)propane-1,2-diol, HC Yellow No. 11, HC VioletNo. 1, HC Orange No. 2, HC Orange No. 3, HC Yellow No. 9, HC Red No. 10,HC Red No. 11, 2-(2-hydroxyethylamino)-4,6-dinitrophenol, HC Blue No.12, HC Yellow No. 6, HC Yellow No. 12, HC Blue No. 10, HC Yellow No. 7,HC Yellow No. 10, HC Blue No. 9, 2-chloro-6-(ethylamino)-4-nitrophenol,6-nitropyridine-2,5-diamine, HC Violet No. 2,2-amino-6-chloro-4-nitrophenol, 4-(3-hydroxypropylamino)-3-nitrophenol,HC Yellow No. 13, 6-nitro-1,2,3,4-tetrahydroquinoxaline, HC Red No. 14,HC Yellow No. 15, HC Yellow No. 14,N2-methyl-6-nitropyridine-2,5-diamine,N1-allyl-2-nitrobenzene-1,4-diamine, HC Red No. 8, HC Green No.1, HCBlue No. 14, and Natural dyes such as Annato, Anthocyanin, Beetroot,Carotene, Capsanthin, Lycopene, Chlorophyll, Henna, Indigo, Cochineal.

Other Features of the Composition of the First Aspect

The composition may comprise one or more radical scavengers, which maybe present in a sufficient amount to reduce damage to the hair. The oneor more radical scavengers may be advantageously selected such that itis not an alkalising agent. The one or more radical scavengers may beselected from the group consisting of: alkanolamines, amino sugars,amino acids, and mixtures thereof.

The one or moreradical scavengers may be selected from the groupconsisting of: monoethanolamine, 3-amino-1-prop anol,4-amino-1-butano1,5-amino-1 -pentanol, 1-amino-2-propanol,1-amino-2-butanol, 1-amino-2-pentanol, 1-amino-3-pentanol,1-amino-4-pentanol, 3-amino-2-methylprop an-1-ol,1-amino-2-methylpropan-2-ol, 3-aminopropane-1,2-diol, glucosamine,N-acetylglucosamine, glycine, arginine, lysine, proline, glutamine,histidine, serine, tryptophan, and potassium, sodium and ammonium saltsof the above, and mixtures thereof. The one or moreradical scavengersmay be selected from the group consisting of: benzylamine, glutamicacid, imidazole, di-tert-butylhydroxytoluene, hydroquinone, catechol,and mixtures thereof. The composition may be substantially free ofradical scavenger.

The composition may comprise a chelant. The composition may comprise achelant in an amount sufficient to reduce the amount of metals availableto interact with composition components. Chelants are also known aschelators and chelating agents. The chelant may be selected from thegroup consisting of: diamine-N,N′-dipolyacid, monoaminemonoamide-N,N′-dipolyacid, andN,N′-bis(2-hydroxybenzyl)ethylenediamine-N,N′-diacetic acid chelants(e.g. EDDS (ethylenediaminedisuccinic acid)), carboxylic acids (e gaminocarboxylic acids), phosphonic acids (e.g. aminophosphonic acids),polyphosphoric acids (in particular straight polyphosphoric acids),salts and derivatives thereof, and mixtures thereof. The chelant may beethylenediamine tetraacetic acid (EDTA) and/or editronic acid. Thechelant may be histidine.

The composition may be substantially free of persulfate. The method maynot encompass or include bleaching the hair.

Exemplary Embodiments of the First Aspect

A solid composition for preparing a hair cosmetic, is provided andcomprises:

-   (a) an aminosilicone polymer, wherein the aminosilicone polymer    comprises amino side chains, and wherein the aminosilicone polymer    as a weight average molecular weight of from 10,000 Dalton to 60,000    Dalton;-   (b) a silicone resin which is a MQ resin;-   (c) an ether of a water-soluble polyhydric alcohol;-   (d) one or more pigments;-   (e) a thickening system comprising:    -   a deposition enhancer, wherein the deposition enhancer is a        hydrophilic and non-ionic polymer, and wherein the deposition        enhancer has a weight average molecular weight of from 700,000        Dalton to 3,000,000 Dalton; and    -   a thickening polymer, wherein the thickening polymer has a        weight average molecular weight of at least 10,000 Dalton, and        wherein the thickening polymer is a cationic thickening polymer        or is a non-ionic thickening polymer.-   The composition may be substantially free of compounds causing    precipitation of any component of the composition when the    composition is in aqueous solution at pH 5 and at 23° C. The    composition may comprise one or more pigments having an average D₅₀    particle diameter of from 5 micron to 60 micron;-   and wherein the composition may comprise a particulate substance    being silica.

A solid composition for preparing a hair cosmetic, may be provided andmay comprise:

-   (a) an aminosilicone polymer, wherein the aminosilicone polymer    comprises amino side chains, and wherein the aminosilicone polymer    as a weight average molecular weight of from 10,000 Dalton to 60,000    Dalton;-   (b) a silicone resin which is a MQ resin;-   (c) an ether of a water-soluble polyhydric alcohol;-   (d) one or more pigments;-   (e) a thickening system comprising:    -   a deposition enhancer, wherein the deposition enhancer is a        hydrophilic and non-ionic polymer, and wherein the deposition        enhancer has a weight average molecular weight of from 700,000        Dalton to 3,000,000 Dalton;    -   a thickening polymer, wherein the thickening polymer has a        weight average molecular weight of at least 10,000 Dalton, and        wherein the thickening polymer is a cationic thickening polymer        or is a non-ionic thickening polymer;        and wherein the composition may be substantially free of        compounds causing precipitation of any component of the        composition when the composition is in aqueous solution at pH 5        and at 23° C.;        and wherein the composition may comprise one or more pigments        having an average D₅₀ particle diameter of from 5 micron to 60        micron;        and optionally further compounds selected from the group        consisting of perfumes and preservatives.

A solid composition for preparing a hair cosmetic, may be provided andmay comprise:

-   (a) from 16% to 43% of an aminosilicone polymer, wherein the    aminosilicone polymer comprises amino side chains, and wherein the    aminosilicone polymer as a weight average molecular weight of from    10,000 Dalton to 60,000 Dalton;-   (b) from 2.0% to 7% of a silicone resin which is a MQ resin;-   (c) from 10% to 20% of an ether of a water-soluble polyhydric    alcohol;-   (d) from 40% to 45% of one or more pigments;-   (e) from 5% to 12% of a thickening system comprising:    -   a deposition enhancer, wherein the deposition enhancer is a        hydrophilic and non-ionic polymer, and wherein the deposition        enhancer has a weight average molecular weight of from 700,000        Dalton to 3,000,000 Dalton;    -   a thickening polymer, wherein the thickening polymer has a        weight average molecular weight of at least 10,000 Dalton, and        wherein the thickening polymer is a cationic thickening polymer        or is a non-ionic thickening polymer;        and wherein the composition may comprise one or more pigments        having an average D₅₀ particle diameter of from 5 micron to 60        micron.

2nd Aspect

The second aspect relates to a method for providing a film comprisingone or more pigments or one or more coloured materials onto keratinfibres, the method comprising applying the composition as set out hereinabove as an aqueous solution onto keratin fibres and allowing thekeratin fibres to dry or drying them.

The method may comprise mixing the composition as set out herein abovewith other materials to form composition applied to hair e.g. an aqueoussolution of the composition as set out herein above.

The method may comprise mixing the composition as set out herein abovewith a solvent. The solvent may be a cosmetically acceptable carrier.The solvent may be water. Water is useful because it provides ahydrophilic phase, which the hydrophilic portions of the components caninteract with. Water is also useful because it provides a fluid phasemeaning that the composition can be in liquid form and therefore easilymixed with other fluids. The composition applied to hair may comprisefrom 40% to 90%, or 50% to 85%, or from 55% to 80% of water. The solventmay comprise water and wherein the composition applied to hair maycomprise from 50% to 85% of water. The composition applied to hair maybe an aqueous, alcoholic or aqueous-alcoholic composition comprising atleast 10% water.

The composition applied to hair may comprise further water-miscible orwater-soluble solvents. The composition applied to hair may comprise atleast one C₁-C₅ alkyl monohydric alcohol, or at least one C₂-C₃ alkylalcohols. The composition applied to hair may comprise ethanol and/orisopropanol. The composition applied to hair may comprise a co-solvent.The co-solvent may be a cosmetically acceptable organic solvent or amixture of solvents with a boiling point below 400° C. The compositionapplied to hair may comprise from 0.1% to 15% co-solvent, or from 1% to10% co-solvent. The co-solvent may be selected from the group consistingof unbranched or branched hydrocarbons, such as pentane, hexane,isopentane; cyclic hydrocarbons, such as cyclopentane and cyclohexane.The composition applied to hair may comprise glycerol, ethylene glycol,propylene glycol, or a mixture thereof.

The composition applied to hair may comprise an anti-freeze agent. Ananti-freeze agent has the advantage that it lowers the freezing point ofa composition applied to hair and consequently prevent the compositionapplied to hair from freezing, which can prevent any unwanted sideeffects of freezing and/or subsequent thawing. The anti-freeze agent maybe a volatile alcohol, for example a volatile alcohol having from 1 to 8carbon atoms and being miscible in water. The composition applied tohair may comprise from 0.5% to 30% of a volatile alcohol, wherein thevolatile alcohol may have from 1 to 8 carbon atoms and is miscible inwater. Miscibility in water is useful in view of the advantages of usingwater as a solvent.

The pH of the composition applied to hair may be from 3.0 to 11.0, orfrom 3.5 to 8.0, or from 3.5 to 5.5, or from 4.0 to 5.0. The pH can beuseful in ensuring cosmetic compatibility and stability of thecomposition applied to hair. For example, a too high or too low pH cancause components to precipitate, which could lead to undesirableresidues on hair.

The composition applied to hair may comprise a pH modifier and/orbuffering agent. The amount can be sufficiently effective to adjust thepH of the composition. Suitable pH modifiers and/or buffering agents foruse herein include, but are not limited to ammonia, alkanolamines suchas monoethanolamine, diethanolamine, triethanolamine, monopropanolamine,dipropanolamine, tripropanolamine, tripropanolamine,2-amino-2-methyl-1-propanol, and 2-amino-2-hydroxymethyl-1,3,-propandioland guanidium salts, alkali metal and ammonium hydroxides andcarbonates, such as sodium hydroxide, sodium silicate, sodium metasilicate and ammonium carbonate, and acidulents such as inorganic andinorganic acids, e.g., phosphoric acid, acetic acid, ascorbic acid,citric acid or tartaric acid, hydrochloric acid, and mixtures thereof.

The composition applied to hair may have a viscosity of from 30 mPa·s to1000 mPa·s. The viscosity is measured at 23° C. using a HAAKE RotationViscometer VT 550 with cooling/heating vessel and sensor systemsaccording to DIN 53019 at a shear rate of 12.9 s⁻¹. The compositionapplied to hair may have a viscosity of from 100 mPa·s to 500 mPa·s, orfrom 150 mPa·s to 450 mPa·s, or from 200 mPa·s to 400 mPa·s, or from 250mPa·s to 350 mPa·s. The composition applied to hair may have a viscosityof from 100 mPa·s to 200 mPa·s. The viscosity range is useful in view ofhelping to prevent the composition from dripping onto clothes and/orsurrounding material. Furthermore, when the viscosity is too high, thecomposition applied to hair cannot easily be mixed.

The composition applied to hair may have a tangent delta of less than 2at an angular frequency of 1 Hz at 23° C. and at 1% strain. Tangentdelta (also known as: tan delta, tan [δ], loss tangent, loss factor) isthe ratio of viscous modulus (G″) to elastic modulus (G′) and is aquantifier of the presence and extent of elasticity in a fluid. How tocalculate the tan delta is shown below:

G^(′) = Storage  Modulus G^(″) = Loss  Modulustan   δ = Loss  Factor$\frac{G^{''}}{G^{\prime}} = {\left. {\tan \mspace{14mu} \delta} \middle| G^{*} \middle| (w) \right. = {{{G^{\prime}(w)} + {{iG}^{''}(w)}} = \sqrt{G^{\prime 2} + G^{''2}}}}$

Further information on equipment and methodology for calculating tangentdelta can be found in the Experimental section below. The compositionapplied to hair may have a tangent delta of from 0.6 to 2 at an angularfrequency of 1 Hz at 23° C. and at 1% strain. The composition may have atangent delta of from 0.6 to 1.5, or from 0.6 to 1.0 at an angularfrequency of 1 Hz at 23° C. and at 1% strain.

The method may comprise drying the keratin fibres with a device selectedfrom the group consisting of blow dryer, heated irons, heated hood, andcombinations thereof. The drying may be carried out using a hair dryeror a drying hood. The drying may be carried out at a temperature of 28°C. to 40° C. The temperature is useful in that it assists in theevaporation of solvent and other volatile compounds and thus allowsexcellent film formation. The method may comprise drying the keratinfibres with a device selected from the group consisting of blow dryer,heated irons, heated hood, and combinations thereof.

The method may comprise applying a composition as set out herein aboveas an aqueous solution onto keratin fibres and allowing the keratinfibres to dry or drying them; and subsequently, applying a formulationcomprising a silicone resin onto keratin fibres and allowing the keratinfibres to dry or drying them. The composition may comprise a whitepigment or a black pigment.

The method may comprise applying a first composition as set out hereinabove as an aqueous solution onto keratin fibres and allowing thekeratin fibres to dry or drying them; and subsequently, applying asecond composition as set out herein above as an aqueous solution ontokeratin fibres and allowing the keratin fibres to dry or drying them;wherein the first composition comprises a first pigment exhibiting afirst colour and the second composition comprises a second pigmentexhibiting a second colour. The first colour may be white or black. Thesecond colour may be neither white nor black. The first pigment maycomprise titanium dioxide or carbon.

3^(rd) Aspect

The third aspect relates to a kit comprising: the composition as set outherein above, or a plurality of compositions as set out herein above,wherein each composition comprises a different pigment or colouredmaterial; and an applicator. The kit may comprise a formulationcomprising pigment and/or coloured material. The kit may consist of apackaging comprising the composition as set out herein above and asponge head; and wherein the composition comprises pigment and/orcoloured material. The kit may comprise a multi-compartment packagecomprising a first compartment and a second compartment; wherein thefirst compartment comprises the composition as set out herein above andthe second compartment comprises the pigment and/or coloured material.

The kit may comprise a first composition as set out herein abovecomprising a first pigment and a second composition as set out hereinabove comprising a second pigment; wherein the first pigment and thesecond pigment exhibit different colours.

4^(th) Aspect

A fourth aspect relates to the use of the kit according to the 3^(rd)aspect for applying pigment and/or coloured material to keratin fibres.

EXAMPLES

The following examples further describe and demonstrate embodimentswithin the scope of the present invention. The examples are given solelyfor the purpose of illustration, and are not to be construed aslimitations of the present invention since many variations thereof arepossible without departing from its scope.

The composition according to the present invention is in solid form. Thefollowing examples provide exemplary compositions as applied to hair.

Composition Applied to Hair Examples

Example Ingredient 1 2 3 4 5 6 7 8 9 10 11 12 BELSIL ADM 10   8   12  15   14   18   15   14   12   15   15   15   8301 E¹ Salcare ® SC 96²0.6  0.75  0.75  0.75 —  0.75  0.75 —  0.75 0.6 0.5  0.75 2-hydroxyethyl— — — — 0.2 — — — — — — — cellulose³ Xanthan gum⁴ — — — — — — — 0.3 — —— — PEG-45M⁵ 0.2 0.3 — — 0.1 0.2 0.2 — — 0.2 0.2 0.2 PEG-23M⁶ — — 0.2 —— — — — 0.2 — — — PEG-90M⁷ — — — 0.1 — — — — — — — — PEG-7M⁸ — — — — 0.3— — — — — — — PEG-180M⁹ — — — — — — — 0.1 — — — — Tergitol^($) — 0.5 —0.5 — — 0.5 — 0.5 0.5 0.5 0.5 Pigment^(§) 5.0 5.0 5.0 4.0 5.0 5.0 5.05.0 5.0 5.0 5.0 5.0 Aquasolved^(#) — — — 2.5 2.5 — — 2.3 — — — — Ethanol1.0 1.5 2.0 — — 1.0 1.5 2.0 — 1.0 1.0 1.0 Preservative* 1.0 2.0 1.5 0.51.0 — — — 1.0 1.0 1.0 1.0 Perfume — 0.1  0.07 0.1 — — — 0.2 0.2 0.1 0.10.1 Deionised water QSP QSP QSP QSP QSP QSP QSP QSP QSP QSP QSP QSP KEY:¹= from Wacker, liquid, microemulsion, aqueous mixture ofpoly[3-((2-aminoethyl)amino)propyl]methyl(dimethyl)siloxane(hydroxyterminated), octamethylcyclotetrasiloxane, MQ resin, ethyleneglycol monohexyl ether and diethyleneglycol monobutylether; ²= Salcare ®SC 96 from BASF, polymer dispersion in oil, which has the INCI name:Polyquaternium-37 (and) Propylene Glycol Dicaprate Dicaprylate (and)PPG-1 Trideceth-6; ³= Cellosize ™ HEC QP 4400 from Dow; ⁴= Keltrol ®from Kelco or Natrosol ® 250 HHR from Herkules; ⁵= POLYOX WSR N-60K fromDow has formula H(OCH₂CH₂)_(n)OH wherein n is an integer and where n hasan average value of 45,000 and the weight average molecular weight is2,000,000 Dalton; ⁶= POLYOX WSR N-12K from Dow has the formulaH(OCH₂CH₂)_(n)OH wherein n is an integer with an average value of 23,000and the weight average molecular weight is 1,000,000 Dalton; ⁷= POLYOXWSR-301 from Dow has the formula H(OCH₂CH₂)_(n)OH wherein n is aninteger with an average value of 90,000 and the weight average molecularweight is 4,000,000 Dalton; ⁸= POLYOX N-750 from Dow has the formulaH(OCH₂CH₂)_(n)OH wherein n is an integer with an average value of 7,000and the weight average molecular weight is 300,000 Dalton; ⁹= POLYOXWSR-308 from Dow, as formula H(OCH₂CH₂)_(n)OH wherein n is an integerand where n has an average value of 180,000 and has a weight averagemolecular weight of 8,000,000 Dalton; ^($)= C11-15 Pareth-9 and is thepolyethylene glycol ether of a mixture of synthetic C11-15 fattyalcohols with an average of 9 moles of ethylene oxide. *=2-phenoxyethanol and/or phenylmethanol; ^(#)= from Firmenich; ^(§)=pigment selected from: mica and/or iron oxides; Colorona Bronze Fine;SynCrystal Almond; Xirona Le Rouge; DUOCROME RV 524C; SynCrystal Jade;Colorona Precious Gold; Ronastar Red; Syncrystal Sapphire; Impact SilverRutile; KTZ Misterioso Pewter; and combinations thereof.In order to create the solid composition according to the presentinvention, the composition components (a) to (e) i e aminosiliconepolymer, silicone resin, ether of a water-soluble polyhydric alcohol,pigment and thickening system comprising selected deposition enhancerand thickening polymer are mixed together by using the quantitiesprovided above. Where the composition after mixing (a) to (e) is not insolid form, vacuum distillation is used to obtain a solid composition byusing a rotary evaporator capable of removing solvents having a boilingpoint of 200° C. or less.

Experimental Dripping Test

Various compositions are tested in order to elucidate advantageousdripping behaviour of various thickening systems. A base composition isprepared that comprises water, an aminosilicone polymer(polydimethylsiloxane polymer having graft amino groups), silicone resin(MQ resin), and mixture of diethyleneglycol monobutylether and ethyleneglycol monohexyl ether. As per the below table, a deposition enhancer ora thickening polymer is added to the base composition in the amounts (wt%) indicated. 0.5 g of pigment is then added to 9.5 g of thiscomposition. The composition is applied to hair and the drippingbehaviour observed and, where relevant, the number of drips in 30seconds counted.

Deposition Thickening Visual observations enhancer polymer onconsistency Dripping test 1 — — Watery 15 drips in 30 s 2 — 1 *   CreamyNo dripping 3 — 0.5 ^(#) Creamy No dripping 4 1 ^(§)   — Gel-like,sticky No dripping 5 — 0.8 ^(#) Creamy No dripping 6 0.2 ^(β) — Watery,stringy 2 drips in 30 s 7 0.2 ^(§) — Watery 2 drips in 30 s Key: * =Cellosize (Hydroxethylcellulose); ^(#) = Salcare SC 96 from BASF; ^(β) =POLYOX WSR 308 (Dow), which has a M. Wt. of 8 million Dalton; ^(§) =Polyox WSR N60K (Dow), which has a M. Wt. of 2 million Dalton.Conclusions: Compositions 2 and 3 performed the best. When comparingcompositions 6 and 7, it is apparent that the higher weight averagemolecular weight of the deposition enhancer caused compositionstringiness. Composition 4 demonstrates that deposition enhancer alonedoes not provide the preferred creamy consistency. Only the compositionscomprising a thickening polymer exhibited the preferred creamyconsistency.

Rheology

The following compositions are prepared.

Thickening Deposition Phenoxy- Water Pigment^(§) Z EtOH polymer*enhancer^(#) ethanol Total A 85 0 15 0 0 0 0 100 B 77.3 5 15 1 0.75 0 1100 C 77.8 5 15 1 0 0.2 1 100 D 77.6 5 15 1 0.25 0.2 1 100 E 77.3 5 15 10.5 0.2 1 100 F 77.1 5 15 1 0.75 0.2 1 100 G 76.8 5 15 1 1 0.2 1 100KEY: Z = Wacker ® HC303 (as per BELSIL ADM 8301 E above commerciallyavailable); EtOH = ethanol; *= Salcare ® SC96 from BASF; ^(#)= PEG-45M(Polyox WSR N-60K) from Dow; ^(§)= copper pigment.The viscosity of these compositions is measured and an averagecalculated. A simple flow viscosity experiment provides information onhow fast the same quantity of composition flows down the same gradientand all other conditions equal. The dripping test is as per above.

Viscosity* Flow viscosity 1 2 3 Average (cm/s) Dripping test A 1.9 2.852.85 2.53 3.1 1 B 100 99.9 100 99.96 2.1 0 C 9.51 8.56 8.56 8.87 7.6 0 D45.6 44.7 43.7 44.66 3.6 0 E 124 123 122 123 2.2 0 F 319 318 317 318 1.50 G 757 755 756 756 1 0 KEY: *viscosity in mPa · s using a Haakeviscometer (64.50 1/s) MV DIN with 5 minute conditioning time.Consequently, compositions B and D to G fall within the viscosity offrom 30 mPa·s to 1000 mPa·s. Composition D has the lowest viscosity outof compositions B and D to G. Composition D has the fastest flowviscosity out of compositions B and D to G. Composition G has thehighest viscosity and also the slowest flow viscosity.

The time-dependent viscoelastic properties in the linear viscoelasticregion with an amplitude sweep are measured and compared. The storagemodulus and tangent delta are measured using a TA-Instruments AR2000exrheometer. In this experiment, different compositions are compared. Thecomponents of the composition are mixed together, and then homogenisedusing an IKA KS 501 digital at 160 rpm and then loaded it onto therheometer. The rheometer is used with the followingspecifications/conditions: upper geometry, 60 mm steel; lower geometry,Peltier Element; temperature, 23° C.; Pre-shear, 5 1/s, 1 min;equilibration, 2 min; normal force, off; gap: 650 μm. An amplitude sweep(strain sweep) was carried out with a strain of between 0.05% and 50%,with log data sampling (10 points/decade) and at a frequency of 1 Hz(6.283 rad/s).

These data are depicted in FIG. 1, which is also summarised in the belowtable.

Compo- Symbol in Thickening Deposition Tangent delta (at 1 sition FIGUREpolymer* agent^(#) Hz and 1% strain) B Δ triangle 0.75 0 is less than 2but greater than 0.6 D X cross 0.25 0.2 is greater than 2 E ⋄ diamond0.5 0.2 is greater than 2 F + plus 0.75 0.2 is less than 2 but greaterthan 0.6 G ◯ circle 1 0.2 is less than 2 but greater than 0.6 KEY: *=Salcare ® SC96 from BASF; ^(#)= PEG-45M (Polyox WSR N-60K) from Dow.

Consequently, compositions D and E do not have a tangent delta of lessthan 2 at an angular frequency of 1 Hz at 23° C.

Color and Hair Performance: Influence of the MQ Resin

The following compositions were prepared (all amounts are in wt %). Acomposition H comprises a MQ resin while a comparative composition Idoes not comprise a MQ resin. The comparative composition I is notwithin the scope of the present invention.

Anti- Thickening Deposition Phenoxy- freeze Water Pigment^(§) Z W EtOHpolymer* enhancer^(#) ethanol agent^($) Total H Qsp 5 15 0 2 0.75 0.2 10.5 100 I Qsp 5 0 15 2 0.75 0.2 1 0.5 100 KEY: Z = Wacker ® HC303(commercially available); W = Wacker ® HC303 as set out herein abovewithout any MQ resin; EtOH = ethanol; *= Salcare ® SC96 from BASF; ^(#)=PEG-45M (Polyox WSR N-60K) from Dow; ^(§)= copper pigment fromColorona ®; and ^($)= C₁₁₋₁₅ Pareth-9 and is the polyethylene glycolether of a mixture of synthetic C11-15 fatty alcohols with an average of9 moles of ethylene oxide.

Hair Strands

-   Caucasian Hair color 4/0 Euro-Natural-Hair-   Hair strands having a width of 1.5 cm and a length of 10 cm.-   Available from Kerling International Haarfabrik

Application of Each of the Compositions H or I on Hair Strands

-   1.0 g of a composition H or a comparative composition I was applied    on 1.0 g of hair strands. The respective composition H or I was    distributed into the hair strands with the help of a brush or a    sponge head. The hair strands were flipped. The respective    composition H or I was further distributed until all hair fibers of    the hair strands were completely and evenly colored.-   Each treated hair strand was blow dried manually with a conventional    blow dryer for 2 minutes. After each 30 seconds, the treated hair    strands were combed from the top to the bottom of the hair strands.

Visual Assessment of the Color Effect/Intensity:

-   The hair strands treated with the composition H were compared to the    hair strands treated with the comparative composition I under a D65    light box. The assessment was rated as follows:

−3 −2 −1 0 1 2 3 Obvious Noticeable Slightly Equal Slightly NoticeableObvious worst worst worst better better betterThe reference was a non-treated hair strand.

-   Hair strands treated with the composition H exhibited a noticeable    better effect on hair than the reference.-   Hair strands treated with the comparative composition I exhibited a    slight worst effect on hair than the reference.-   When the composition comprises a MQ resin, the color effect on hair    is better noticeable than when the composition does not comprise a    MQ resin.

Effect of Hair Wash

-   The hairs strand treated with the respective composition H or I were    washed for 30 seconds with water then 30 seconds with 0.5 mL of    Wella Professionals Brilliance Shampoo, and then 30 seconds with    water.-   Each treated hair strand was blow dried manually with a conventional    blow dryer for 2 minutes. After each 30 seconds, the treated hair    strands were combed from the top to the bottom of the hair strands.-   The hair strands treated with the composition H showed a good    pigment adhesion to the hair, by visual assessment.-   However, the hair strands treated with the comparative composition I    only showed a slight pigment adhesion to the hair, by visual    assessment.

Hair Feel

-   The hair strands treated with the respective composition H or I were    pulled through thumb and index fingers. The treated hair strands    were assessed versus an untreated hair strand. The hair strands    treated with the composition H showed a noticeable coated effect.    However, the hair strands treated with the comparative composition I    only showed a slight coated effect.

Water Dipping Test

-   The hair strands treated with the respective composition H or I were    dipped for 15 times for 15 seconds in 200 mL of distillate water. A    picture was taken after the pigments have sedimented. It has been    observed that the hair strands treated with the composition H lost    few pigments. However, the hair strands treated with the comparative    composition I lost much more pigments versus the hair strands    treated with the composition H.

CONCLUSION

-   When the hair strands are treated with the composition H which    comprises a MQ resin, versus the comparative composition I, the    treated hair strands exhibited an improved colored performance, with    an increased pigment adhesion on hair, and a better resistance to    wash fastness.

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm. ”

Every document cited herein, including any cross referenced or relatedpatent or application, is hereby incorporated herein by reference in itsentirety unless expressly excluded or otherwise limited. The citation ofany document is not an admission that it is prior art with respect toany invention disclosed or claimed herein or that it alone, or in anycombination with any other reference or references, teaches, suggests ordiscloses any such invention. Further, to the extent that any meaning ordefinition of a term in this document conflicts with any meaning ordefinition of the same term in a document incorporated by reference, themeaning or definition assigned to that term in this document shallgovern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is thereforeintended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed is:
 1. A solid composition comprising: (a) anaminosilicone polymer, wherein the aminosilicone polymer comprises aminosidechains, and wherein the aminosilicone polymer has a weight averagemolecular weight of from about 10,000 Dalton to about 60,000 Dalton; (b)a silicone resin, wherein the silicone resin is a MQ resin; (c) an etherof a water-soluble polyhydric alcohol; (d) one or more pigments or oneor more coloured materials; (e) a thickening system comprising: adeposition enhancer, wherein the deposition enhancer is a hydrophilicand non-ionic polymer, and wherein the deposition enhancer has a weightaverage molecular weight of from about 700,000 Dalton to about 3,000,000Dalton; and a thickening polymer, wherein the thickening polymer has aweight average molecular weight of at least about 10,000 Dalton, andwherein the thickening polymer is a cationic thickening polymer or is anon-ionic thickening polymer.
 2. The composition of claim 1, wherein thecomposition comprises one or more pigments having an average particlesize of from about 5 μm to about 60 μm.
 3. The composition of claim 1,wherein the composition is in powder form.
 4. The composition of claim1, wherein the composition comprises one or more coloured materials,wherein the one or more coloured materials is selected from the groupconsisting of: coloured fibres, coloured beads, coloured particles whichare nano-particles, coloured polymers comprising covalently attacheddyes, particles having diffraction properties, and combinations thereof.5. The composition of claim 1, wherein the one or more pigments areselected from the group consisting of metal oxides, hydroxides and oxidehydrates, mixed phase pigments, sulfur-containing silicates, metalsulfides, complex metal cyanides, metal sulfates, chromates andmolybdates, and the metals themselves, and combinations thereof.
 6. Thecomposition of claim 1, wherein the composition comprises from about 35%to about 60% of the one or more pigments, by total weight of thecomposition.
 7. The composition of claim 1, wherein the depositionenhancer conforms to the formula H(OCH₂CH₂)_(n)OH wherein n has anaverage value of from about 20,000 to about 50,000.
 8. The compositionof claim 1, wherein the aminosilicone polymer is a polydimethylsiloxanepolymer having a sidechain with from 3 to 8 carbon atoms.
 9. Thecomposition of claim 1, wherein the ether of a water-soluble polyhydricalcohol is selected from the group consisting of diethylene glycolmonobutyl ether, ethylene glycol monohexyl ether, and a mixture ofdiethylene glycol monobutyl ether and ethylene glycol monohexyl ether.10. The composition of claim 1, wherein the composition is anhydrous.11. The composition of claim 1, wherein the aminosilicone polymer is apolydimethylsiloxane polymer having graft amino groups.
 12. Thecomposition of claim 1, wherein the composition is substantially free ofcompounds causing precipitation of any component of the composition whenthe composition is in aqueous solution at pH of about 5 and at about 23°C.
 13. The composition of claim 1, wherein the deposition enhancerconforms to the formula H(OCH₂CH₂)_(n)OH wherein n has an average valueof from about 40,000 to about 50,000.
 14. A method for providing a filmcomprising one or more pigments or one or more coloured
 1. ls ontokeratin fibres, the method comprising applying the composition of claim1 as an aqueous solution onto keratin fibres and allowing the keratinfibres to dry or drying them.
 15. A kit comprising: the composition ofclaim 1, or a plurality of compositions of claim 1, wherein eachcomposition comprises a different pigment or coloured material; anapplicator.